Thank you for the question.
Yes, you can put baking soda on sores. Check out Dr. Charlotte Grayson's article on Managing Genital Herpes Symptoms and Outbreaks for more information.
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Dr. Charlotte Grayson has great suggestions, but one. Do NOT take a warm bath. Herpes feeds off heat. It will spread in warm water. Don't know why on earth people suggest this. It's really contraindicated.